Click the color in the adjusted column in the color adjustment drawer to set it to set the target color you want. Pixels with color close to the original color will be adjusted to the target color. Letting the target color be the same as the original color for a color adjustment makes colors like the original color remain unchanged.
A few color adjustments are created as default. They make black, white, red, green and blue stay constant which limits the effect of color adjustments you add. Disable these, or completely remove them if they conflict with the color adjustments you want to do. You can change the default settings for new images under the Tint menu.
A color adjustment can be applied as an RGB (Red, Green, Blue) change, or as a change in HSB (Hue, Saturation, Brightness). This gives slightly different effects. RGB is faster and usually a good setting. Read more about HSB by clicking the "Working with hue..." link below.
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